I found these pages useful:
http://www.databasejournal.com/features/postgresql/article.php/3288951 evaluates MySQL v PostgreSQL
http://www.redhat.com/docs/manuals/database/ may be helpful to those seeking to illustrate commercial support for PostgreSQL
http://panoptic.com/wiki/aolserver/43 lists sites using AOLServer, including several major AOL services. It should be edited to reflect OACS/.LRN users (any volunteers?)