yes, using SQL schemas would certainly make the system prettier.
The reason, why SQL schemas are not used in OpenACS is for historical reasons: when the postgres port was done, schemas were not supported by postgres. When using schemata, it would certainly make sense to move not only stored procedures into the schema space, but as well the tables defined by the packages, every package could be contained in a tcl namespace and sql schema ... and then, one should do the same for oracle as well. As you mentioned the benefit is not huge; from my experience is more likely that you get hate-mails, when you break something, than love-mails, when the components work as before.
I see a move to SQL schemas of less priority than Step-2 above (currently, debugging the function with the varying argument lists is painful, querying the default values from the postgres meta data does not work, we have hacks in OpenACS to work around this).