Forum OpenACS Q&A: Re: Server startup failed: Error during bootstrapping
Or you're starting AOLserver in such a way that it can't find your PostgreSQL libraries, as you imply above. How are you starting AOLserver? Have you verified that it is in fact seeing the environment variables above. I assume that the "D_LIBRARY_PATH" typo occurs only in your post above, not in your actual code.
Why are you using such ancient versions of AOLserver and PostgreSQL?