Hi Iuri,
That last bit indicates the "Mail From" is empty:
status=bounced (host smtpout.secureserver.net[68.178.252.101] said: 550 <> Sender Rejected - MAILFROM must be a valid domain.
Compare the email headers on the rejected email, versus the original for clues. The headers contain a log of all the smtp related activity.
This URL may be helpful:
https://serverfault.com/questions/147921/forcing-the-from-address-when-postfix-relays-over-smtp
Otherwise consider posting at serverfault or one of the other stackexchange hosted admin sites to resolve.
best wishes,
Ben
